Message: | Properties and applications
As a dry solid, K2FeO4 is stable. It decomposes with evolution of O2 in neutral water, and especially rapidly in acidic water. At high pH, aqueous solutions are stable. The deep purple solutions are similar in appearance to potassium permanganate (KMnO
4). It is stronger oxidizing agent than the latter.
Because the side products of its redox reactions are rust-like iron oxides, K2FeO4 has been described as a "green oxidant." It has been employed in waste-water treatment as an oxidant for organic contaminants and as a biocide. Conveniently, the resulting reaction product is iron(III) oxyhydroxide, an excellent flocculant.
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